Why are there exceptions like chromium? Isn't chemistry supposed to have rules?
Chemistry does have rules—the rule is that electrons minimise energy. Chromium's exception (Ar 3d⁵ 4s¹ instead of 3d⁴ 4s²) occurs because a half-filled d-subshell is extra-stable. It's not random; it's following the energy rule more closely than a simpler pattern would.
