How do I know when to use Roman numerals in a compound name?
Use Roman numerals for transition metals and other elements with variable oxidation states. For example, copper forms Cu⁺ and Cu²⁺, so you write copper(I) chloride and copper(II) chloride to show which. Main group metals (Na, Ca, Al) don't need Roman numerals because their charge is predictable from position in the periodic table.
